The Shortwave Infrared (SWIR) region occupies the spectrum band typically spanning from approximately 1µm to 3µm, positioned between the near-infrared (NIR) and mid-infrared (MWIR) regions. Thi sparticular spectrum has many modern applications.
Luminescent downconverters operate on the principle of spontaneous emission, where high-energy excitation photons are absorbed, undergo internal relaxation, and are subsequently re-emitted as lower-energy photons.
In this approach, colloidal quantum dots (QDs) are utilized (Binary blends) as the active luminescent media to achieve sharp spectral tunability and efficient downconversion. However, a major bottleneck in operating downconverters at high efficiencies is heat generation under intense optical pumping and thermal relaxation, which requires careful thermal management to prevent degradation and thermal quenching.
QDs in PMMA
Drop casting deposition technique
The QDs were dispersed in a PMMA polymer to reduce thermal stress due to thermal relaxation during spontaneous emission. Once the QDs are mixed, a thin film was formed via dropcasting. Based on the mould, the DC can be of any shape or size. However, thermal conductivity of PMMA is not excellent. Due to high optical absorption, there is tremendous amount of heat generated which resides in the PMMA. Standalone DCs also have bi-directional emission which is undesirable for many applications. Further optical and thermal optimisations were done to maximise performance.
The standalone DC was placed on a DBR substrate to have a unidirectional emission. DBR also acts as a heatsink and pushes teh DC to operate at higher excitation powers. Finally encapsulating with a cheap single polished optically transparent high thermal conductive sapphire substrate allows high emitting power density of > 380 mW/cm² . The Binary blend allowed in tuning the emission wavelength (in the SWIR range) via particle size selection. Such high power SWIR emitters allowed to demonstrate various real world applications.
Imaging setup
Visible Image
SWIR image with 1140 nm illumination
SWIR image with 1380 nm illumination
See-through plastic
Visible image of Si wafer
SWIR image of Si wafer
Eye-safe SWIR imaging
Vein imaging